A teaching tape for LQ-07, Fluorescence Energy Budget and Stokes's Rule

Journey I Stage G: The Fluorescence Energy Accounting

Interactive journey stage examining Stokes's rule, deviation cases, and weak-illumination proportionality.

Open LQ-07 with these settings

Where it starts

The settings the tape begins from, under the constant set modern-si-2019. Values are the model's own, not the laboratory control's display: a radius of 5e-7 is half a micrometre.
SettingValue
Exciting Frequency ν₁ (nu1)850
Emitted Frequency ν₂ (nu2)850
Absorbed Quanta k (multiQuantumK)1
Absorbed Optical Power (absorbedPowerMicrowatts)1
Quantum Yield Y (quantumYield)0.5

What it changes, and what to expect

  1. Where it starts, before anything changes

    Emitted light at the absorbed frequency, where the ledger just balances

    The walkthrough opens with the emitted light at the same frequency as the absorbed light, which is the edge of what a single quantum can pay for: the energy going out equals the energy coming in and nothing is left for anything else. Stokes's rule says the emitted frequency does not exceed the absorbed one, and this is that limit rather than a comfortable case inside it. The next step asks for more than the quantum has.

  2. Set Emitted Frequency ν₂ (nu2) to 900 changes what the run starts from

    The Single-Quantum Ledger

    Single-quantum energy accounting: h*nu1 = h*nu2 + E_other.

    What the author recorded that a reader should see here.
    QuantityExpectedUnder
    energyDeficitEv0.206783 eVmodern-si-2019

These are the values the tape's author recorded, not a result this page computed. Nothing here runs the instrument. Open LQ-07 with these settings: the link opens it with them already in place. Compare what it gives you with what is recorded here. The settings travel in the link and the laboratory reads them as it loads, so without JavaScript it opens at its worked example instead.

What these numbers were recorded under

The identities the recorded values belong to. The same instrument run under a different seed, or under a later version of its model, gives different numbers without either set being wrong.
IdentityRecorded as
Modelfluorescence-budget-reference version 1
Seed0
Random-stream semanticsversion 1

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